湿地土壤和沉积物异化铁还原过程研究进展     

朱晓艳  袁宇翔  宋长春  姜明 《湿地科学》2020,18(1):122-128

异化铁还原是湿地土壤和沉积物中重要的生物地球化学过程,也是有机质矿化的主要途径之一。湿地干湿交替等过程会使土壤的氧化还原状态发生改变,影响铁元素及与其相关的元素的迁移和转化。总结了湿地土壤和沉积物中异化铁还原过程及其与碳、磷、硫等元素在生物地球化学循环关键过程中的相互作用,阐述了湿地土壤和沉积物中异化铁还原过程对微量金属元素迁移和转化的影响,分析了影响湿地土壤和沉积物异化铁还原过程的主要环境因子。未来相关研究应集中于湿地土壤和沉积物中异化铁还原微生物分析和纯化、不同有机质形式对异化铁还原过程的影响以及异化铁还原对土壤有机质矿化的贡献。  相似文献   

Nitrogen fixation driven by mesoscale eddies and the Kuroshio Current in the northern South China Sea and the East China Sea     

Liuyang Li  Chao Wu  Jun Sun  Shuqun Song  Changling Ding  Danyue Huang  Laxman Pujari 《海洋学报(英文版)》2020,39(12):30-41

N₂ fixation rates (NFR, in terms of N) in the northern South China Sea (nSCS) and the East China Sea (ECS) were measured using the acetylene reduction assay in summer and winter, 2009. NFR of the surface water ranged from 1.14 nmol/(L·d) to 10.40 nmol/(L·d) (average at (4.89±3.46) nmol/(L·d), n=11) in summer and 0.74 nmol/(L·d) to 29.45 nmol/(L·d) (average at (7.81±8.50) nmol/(L·d), n=15) in winter. Significant spatio-temporal heterogeneity emerged in our study: the anticyclonic eddies (AE) (P<0.01) and the Kuroshio Current (KC) (P<0.05) performed significantly higher NFR than that in the cyclonic eddies or no-eddy area (CEONE), indicating NFR was profoundly influenced by the physical process of the Kuroshio and mesoscale eddies. The depth-integrated N₂ fixation rates (INF, in terms of N) ranged from 52.4 μmol/(m2·d) to 905.2 μmol/(m2·d) (average at (428.9±305.5) μmol/(m2·d), n=15) in the winter. The contribution of surface NFR to primary production (PP) ranged from 1.7% to 18.5% in the summer, and the mean contribution of INF to new primary production (NPP) in the nSCS and ECS were estimated to be 11.0% and 36.7% in the winter. The contribution of INF to NPP (3.0%–93.9%) also decreased from oligotrophic sea toward the eutrophic waters affected by runoffs or the CEONE. Furthermore, we observed higher contributions compared to previous studies, revealing the vital roles of nitrogen fixation in sustaining the carbon pump of the nSCS and ECS.  相似文献   

基于生命周期的北京风味餐厅食物消费温室气体排放与减排案例分析     

张孟蓉  陈莎  李素梅 《气候变化研究进展》2021,17(2):140-150

减少粮食浪费不仅关乎粮食安全,而且对于温室气体减排与生态环境保护也至关重要。本文基于生命周期理论,构建了餐厅食物消费模型;然后通过对北京某风味餐厅的现场调研,量化评估了餐厅每人次产生的平均温室气体排放量,并对餐厅剩余食物产生的原因以及通过减少餐厅食物剩余带来的温室气体减排潜力进行了系统分析。研究结果表明,一个中等规模的北京风味餐厅的总温室气体排放量可达每年225.28 t CO₂当量（CO₂e),即2.50 kg CO₂e/人次;人均每餐食物剩余为97.2 g。朋友聚餐以及其他公共环境中消费的食物剩余量均明显高于普通日常就餐,点菜过多和口味与想象不符是产生剩余的重要原因;而学历、年龄较低的消费者更容易产生食物浪费。核算结果表明,在不产生食物浪费的情况下,可减少10.55%来自于餐厅食物消费的温室气体排放,平均约为0.26 kg CO₂e/人次。通过与食物消费相关的温室气体减排分析,以及制定可行的政策,不仅可以减少温室气体排放,而且可以推进可持续消费发展。  相似文献   

Multi-factor sensitivity analysis on the stability of submarine hydrate-bearing slope     

《China Geology》2018,1(3):367-373

There are many factors affecting the instability of the submarine hydrate-bearing slope (SHBS), and the interaction with hydrate is very complicated. In this paper, the mechanical mechanism of the static liquefaction and instability of submarine slope caused by the dissociation of natural gas hydrate (NGH) resulting in the rapid increase of pore pressure of gas hydrate-bearing sediments (GHBS) and the decrease of effective stress are analyzed based on the time series and type of SHBS. Then, taking the typical submarine slope in the northern South China Sea as an example, four important factors affecting the stability of SHBS are selected, such as the degree of hydrate dissociation, the depth of hydrate burial, the thickness of hydrate, and the depth of seawater. According to the principle of orthogonal method, 25 orthogonal test schemes with 4 factors and 5 levels are designed and the safety factors of submarine slope stability of each scheme are calculated by using the strength reduction finite element method. By means of the orthogonal design range analysis and the variance analysis, sensitivity of influential factors on stability of SHBS are obtained. The results show that the degree of hydrate dissociation is the most sensitive, followed by hydrate burial depth, the thickness of hydrate and the depth of seawater. Finally, the concept of gas hydrate critical burial depth is put forward according to the influence law of gas hydrate burial depth, and the numerical simulation for specific submarine slope is carried out, which indicates the existence of critical burial depth.  相似文献   

温室气体排放的环境库兹涅茨曲线检验与减排路径的冲击动态——基于黑龙江省统计核算数据   总被引：1，自引：0，他引：1  

张滨  吕洁华 《气候变化研究进展》2019,15(1):84-94

基于2001-2015年黑龙江省温室气体排放统计核算数据,对地区GDP与温室气体排放的环境库兹涅茨曲线关系检验呈现倒U型,预期2019年达到理论拐点;通过偏最小二乘回归模型得到4个减排路径的年平均减排效果顺序依次为单位GDP化石能源消费量减少、经济结构调整、人均GDP增长、贸易结构变化;减排路径对应脉冲响应函数的动态冲击效果分别为波动性增排、收敛性减排、发散性减排、转变的排放作用;推动黑龙江省温室气体减排的路径顺序为控制化石能源消费量、优化经济结构、发展低碳经济、调整贸易结构。  相似文献   

绿色交通目标下集装箱“公转铁”的CO2减排潜力评估     

陶学宗  吴琴  尹传忠 《气候变化研究进展》2019,15(6):660-669

为提高集装箱“公转铁”减排潜力评估结果的准确性,在分析“公转铁”减排原理的基础上,综合考虑空箱调运和重箱运输“门到门”运输链的干线运输、端点装卸、电力设备作业、集卡短驳、公铁中转等排放,引入反映活动类型、设备结构、能源生命周期排放的参数,对作业活动-方式结构-能耗强度-排放因子（ASIF）方法进行改进,建立“公转铁”减排潜力评估框架。以义乌—宁波港域出口集装箱运输为例,通过实地调研和公开文献获取数据,进行实证研究。结果表明,如果忽略必要因素将会导致每TEU运输需求“公转铁”的CO₂减排率被高估0.50~36.73个百分点;最佳“公转铁”情景可减排3.42万t CO₂,相应减排率为13.58%。研究结果可为政府相关部门客观评估“公转铁”的减排潜力、制定有效的“公转铁”政策措施提供理论支持。  相似文献   

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD     

Li Q.  Bao Z. 《大地构造与成矿学》2018,(4):699-717

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.  相似文献   

基于边坡稳定性计算方法比较分析          下载免费PDF全文

陈卫华  胡福洪  陈锋 《探矿工程》2018,45(9):71-74

将强度折减法应用于边坡稳定性分析中,折减土体强度,代入有限元程序进行计算,直至计算不收敛,此时的折减系数即为安全系数。结合工程实例,将强度折减法应用于边坡稳定性的分析,利用瑞典圆弧法,结合岩土工程设计类软件天汉以及有限元分析软件ABAQUS分析边坡稳定性,并对安全系数进行对比,3种计算方法得出的安全系数差别不大,安全系数精度都能满足工程要求。  相似文献   

Os水吸收液ICP-MS测量信号强度衰减原因研究     

周利敏  李超  李欣尉  赵鸿  屈文俊  杜安道 《岩矿测试》2018,37(4):431-438

蒸馏法能从样品中有效分离出OsO_4,吸收液直接用于ICP-MS测定,是辉钼矿Re-Os定年的关键技术环节。但实验发现,长时间放置的吸收液中Os信号强度显著降低。根据OsO_4化学性质推测原因在于一是挥发使吸收液Os含量减少,二是还原使+8价Os变成低价态,气态比例降低,若雾化效率不变,进入质谱仪的Os减少,两者都会导致信号降低,但具体影响情况不明,需深入研究。本文利用辉钼矿标准物质制备不同放置时间、酸度和温度的吸收液,对比上述条件对ICP-MS信号强度的影响。实验时将残余吸收液与稀释剂、氧化剂封入Carius管加热蒸馏,测定Os含量。结果表明:吸收液放置时间越长,酸度越低,温度越高,信号降幅越大,幅度达到3.2%~68.6%。室温下放置相同时间,低酸度吸收液的Os保存率高于高酸度吸收液,但Os信号强度低于后者,证明了挥发和还原共同导致信号衰减,且还原是主导原因。本文提出,冷冻(-18℃)可抑制OsO_4挥发,提高酸度(约3.5 mol/L)可减弱OsO_4还原,两者结合抑制信号衰减,提高了蒸馏法的灵活性和适用性。  相似文献   

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)     

V.V. Ryabov  O.N. Simonov  S.G. Snisar  A.A. Borovikov 《Russian Geology and Geophysics》2018,59(8):945-961

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.  相似文献